Acetic acid

10 May 1999 00:00  [Source: ICB]

Supply/demand



Two factors are likely to help the balance in the European market in 1999. The first is the blockade on Serbia which has eliminated Serbian exports to Europe. The plant, rated at 100 000 tonne/year, had been running at around 60 000-70 000 tonne/year. Sources suggest that even if the plant remains undamaged, logistical links and infrastructure have been damaged and it is unlikely that the material will reappear on the European market in 1999. Celanese's shutdown of the Frankfurt plant late 1999 will be brought forward to July, with provision made to import material from the US. Downstream demand, especially from Europe's PTA sector, has been hit by new production outside Europe. Global demand was 6.0m tonne in 1998, according to Tecnon consultant Bill Tollett. Global capacity is much higher - around 7.8m tonne/year. BP Amoco and Celanese have over 50% of the world's production between them. Other producers like Acetex, Daicel, Millennium and Eastman are major regional players.

Uses



Principal chemical uses are as a chemical intermediate and solvent in chemical reactions. Vinyl acetate monomer, used to make protective coatings, adhesives and plastics, is the largest, taking around 40% of global production. PTA production accounts for around 14%, solvent esters 13% and acetic anhydride, used primarily in cigarette filters, about 12%.

Technology



Around 55% of global production uses the methanol carbonylation process developed by Monsanto in the 1960s. This involves combining carbon monoxide and methanol in the presence of an appropriate catalyst. Celanese and BP Amoco have emerged as major players partly due to their strong technology base, with both having developed the original methanol carbonylation route.

###7631###

Celanese patented its AO technology in 1995, which has allowed the company to run facilities with capacities approaching 1m tonne/year. BP Amoco's growth stemmed from its acquisition of Monsanto's technology when the company left the market. After three years of development, BP Amoco patented its Cativa methanol carbonylation process which uses iridium instead of the original rhodium catalyst. Benefits include reduced capital cost and fewer by-products.

Other companies developing routes to acetic acid include Haldor Topsoe and Wacker Chemie. Wacker Chemie anticipates building a commercial scale plant should trials at a pilot scale plant proceed well.

Pricing



Low methanol prices and the weak Asian economy have led to contract prices falling steadily over the last five quarters. However, some recovery in activity in Asia and a slight rise in the methanol price suggests that a second quarter rollover of Europe's first quarter DM850-970/tonne FD is possible. In Asia first quarter prices were agreed at $380/tonne CFR. However, Asian second quarter prices, which tend to be a pointer for European prices, have not been agreed so there is still a degree of uncertainty over Europe's second quarter pricing. Russian spot material is said to have been available in Finland at $250/tonne fob.

Producers say the removal of Serbian sales from the European market is a positive factor because the MSK material had in the past undermined pricing.

GLOBAL ACETIC ACID PRODUCTION, '000 TONNE/YEAR*





Company Location Capacity


Acetex Pardies, France 400


Air Products Calvert City, Kentucky 60


BP Hull, UK 750


Sterling Texas City, US1 450


BP/Petronas Kerteh, Malaysia2 500


Samsung/BP Ulsan,South Korea 350


Yangtze River Sichuan, China3 150


Acetyls


Celanese Clear Lake, US 1000


Pampa, Texas 253


Edmonton, Canada4 90


Cangrejera, Mexico 175


Celaya, Mexico 70


Frankfurt, Germany5 180


Knapsack, Germany 70


Singapore6 500


Wacker Burghausen, Germany7 80


China (over 50 producers) 900


Craiova Romania 43


Chang Chun Miaoli, Taiwan 80


CPDC Ta-she, Taiwan 100


Daicel/ Aboshi, Japan 400


Kyoda Sakusan


Eastman Kingsport, Tennesee 186


Ercros Tarragona, Spain8 100


Millenium Deer Park, Texas 450


MSK Kikinda, Serbia 100


Nevinnomyssk Russia 150


Nippon Mitzushima 90


Synthetic


Rhodia/ Cabo, Brazil 70


Alcoolquimica


Rhodia Paulinia, SP9 73


Severodonetsk Ukraine 150


Showa Denko Oita, Japan 150


*Plants over 50 000 tonne/year capacity1marketed by BP; 2onstream Q4 1999; 3Sichuan Vinyls and BP jv; 4expanding to 130 000 tonne/year; 5to be mothballed mid-1999; 6onstream July 2000; 750%-owned by Hoechst;8mothballed; 9mothballed





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