Styrene

26 October 1998 00:00  [Source: ICB]

Steady demand growth in Europe and the rest of the world is forecast for the next few years

Supply/demand



Total styrene capacity in northwest Europe is put at just over 4.8m tonne/year and will reach more than 5.6m tonne/year in 2000. New capacity is being built by Basell (BASF/Shell) and Repsol, with Lyondell Chemical's (Arco) project now postponed to 2002-03.

Demand growth in western Europe is estimated at 2.6%/year while east European consumption is expected to recover to 4.9%/year through to 2002. World demand is forecast to grow at 3.8%/year for the next four years, falling to 3.5%/year thereafter. Global operating rates will fall to the mid-80% levels to 2002 after which industry experts expect them to start recovering, maybe reaching 88-90% in 2005.

Uses



Polystyrene is the largest derivative accounting for about two-thirds of consumption. Styrene is also used to make styrene-butadiene rubber, acrylonitrile-butadiene-styrene (ABS) resins and emulsion polymers whose end uses include packaging, construction, automotive and household goods.

Health & safety



Styrene is a colourless oily liquid with an aromatic odour. It is a highly flammable and reactive chemical and a fire and explosion hazard. It is classified as a mutagen (causes genetic changes) and exposure can irritate eyes, nose and throat.

Technology



The traditional aluminium chloride catalyst used in the alkylation of benzene with ethylene to ethylbenzene (EB) is being replaced with zeolite catalyst technology. Around 90% of styrene is then produced commercially by the dehydrogenation of EB in the presence of steam over an iron oxide catalyst in either fixed bed adiabatic or tubular isothermal reactors.

Other routes include co-production with propylene oxide (PO/SM) from EB hydroperoxidation, and oxydehydrogenation of EB with air. Butadiene-based processes have been developed to make EB (DSM/Stamicarbon) and styrene (Dow Chemical) but are not believed to have been commercialised.

###7079###

EUROPEAN STYRENE CAPACITY, '000 TONNE YEAR





Company Location Capacity


Arpechim Pitesti, Romania 80


BASF Antwerp, Belgium 500


Ludwigshafen, Germany 510


BP Chemical Marl, Germany 380


Baglan Bay, UK 140


Dow Chemical Terneuzen 3, Netherlands 500


Terneuzen 4, Netherlands 525


DSM Beek, Netherlands 27


Elf Atochem Carling, France 330


Gonfreville, France 390


EniChem Mantova, Italy 350


Mantova, Italy 150


Hythe, UK 60


Kaucuk Kralupy, Czech Republic 100


Neftochim Burgas, Bulgaria 40


Oswiecim Chemical Works


Oswiecim, Poland 80


Petrocel Teleajen, Romania 50


Repsol Puertollano, Spain 150


ROW Wesseling, Germany 365


Shell Chemicals Moerdijk, Netherlands 400


New capacity


Basell* Moerdijk, Netherlands 550 Q2 1999


Lyondell Chemical Rotterdam, Netherlands 640 postponed


Repsol Tarragona, Spain 340 H1 1999


* BASF/Shell Chemicals production jv


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