Methanol CAS No: 67-56-1

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Methanol is used in Gasoline additives (source BP)The three largest derivatives of methanol are formaldehyde, methyl tertiary butyl ether (MTBE) and acetic acid. However, methanol is seeing growing demand in fuel applications such as dimethyl ether (DME), biodiesel and the direct blending into gasoline.

 

Methanol markets have been reasonably balanced for the last few years but in 2008 they moved into oversupply with demand deteriorating due to the faltering economic growth. In particular, demand for formaldehyde, methanol's largest derivative, has been impacted by the downturn in the automotive and construction industries.

 

The strongest growth in methanol demand will be in Asia with the majority of the increase in China. New fuel uses for methanol such as gasoline blending, DME and biodiesel will help support this growth.

 

Nearly all methanol production is based on low pressure processes consuming natural gas, naphtha or refinery light gas. Synthesis gas from a reformer is fed to the methanol converter where the methanol synthesis takes place in the presence of copper-based catalysts. Plant designers are developing very large capacity plants in the 5000-10,000 tonne/day range.

 

Methanol is a colourless, volatile and flammable liquid with a characteristic odour. It is a fire and explosion hazard when exposed to heat, flame or oxidisers.

Methanol Price Reports

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Methanol Uses and Outlook

The three largest derivatives of methanol are formaldehyde, methyl tertiary butyl ether (MTBE) and acetic acid. However, methanol is seeing growing demand in fuel applications such dimethyl ether (DME), biodiesel and the direct blending into gasoline.
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Methanol Process Technologies

From the early 1800s until the mid-1920s, the distillation of wood to make 'wood alcohol' was the major source of methanol. According to some statistics, methanol production reached 30,000 tonnes in 1923, consuming some 3m tonnes of wood feedstock. However, this inefficient method of methanol production was quickly replaced by large scale processes based on hydrogen-carbon oxide mixtures introduced in the 1920s.
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Methanol Plants and Projects

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Methanol Synonyms & Abbreviations

  • Carbinol
  • Metanol
  • Methyl alcohol
  • Methyl hydrate
  • Methyl hydroxide
  • Monohydroxymethane
  • Wood alcohol
  • MeOH

Methanol Properties

Auto-ignition temperature oC
385
Boiling point oC
65
Explosive limits, vol% in air
6-35.6
Flash point oC c.c
12
Melting point oC
-98
Octanol/water partition coefficient (log Pow)
-0.82 / -0.66
Relative density (water = 1)
0.79
Relative density of the vapour/air-mixture at 20oC (air = 1)
1.01
Relative vapour density (air = 1)
1.1
Vapour pressure (kPa at 20oC)
12.3

 
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