The global Isocyanates markets are covered weekly by ICIS in Asia, the Middle East, Europe and the US. All the reports have price assessments on methyl di-p-phenylene isocyanate (MDI) and toluene di-isocyanate (TDI) for spot business and, where applicable, contract or domestic activity.
The up-to-date market news and analysis is collated by our locally based reporters and includes regional activity, upstream and downstream movements, production schedules, graphs and, in some instances, historical data. This provides you with a valuable tool to base your commercial judgements on.
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Isocyanate overview Transcript
Toluene diisocyanate or TDI and methylene di-p-phenylene isocyate or MDI are the most common types of aromatic isocyanates. They are used mainly in the production of flexible and rigid polyurethane or PU foams.
Minor applications include coatings and adhesives. Most TDI output goes into the furniture and automotive sectors, and most MDI into construction. So demand for isocyanates is closely linked with economic performances.
Other factors which impact the price of isocyanates are the supply and feedstock values such as benzene and toluene which are in turn heavily dependent on crude futures pricing. China is the main user of TDI and MDI in Asia.
It has the largest manufacturing base due to a continuous increase in local demand and is the leading exporter for finished goods. Both TDI and MDI are greatly dependent on spot trades which are primarily driven by traders and producers.
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Isocyanates: Market overview
Updated to Q3 2016
US toluene di-isocyanate (TDI) markets faced upward price pressure from tight global supply and producers’ increase initiatives for July. A force majeure on TDI production in the US lent additional support to the hike proposals.
US methyl di-p-phenylene isocyanate (MDI) prices were projected to remain stable into July, despite US producers’ price increase initiatives.
European MDI prices are predicted to firm as the market becomes tighter due to unplanned maintenance. This may be offset by the market’s transition into the quieter summer period. European TDI prices will likely see more significant hikes in Q3 as production issues are predicted to continue. At the time of writing, producer Borsodchem was due to enter turnaround on 8 July.
Asian MDI and TDI import prices are likely to trend softer in Q3 following their increases in Q2. MDI prices will be weighed by lacklustre demand in the current lull demand season amid ample spot availability. The surge in TDI prices will likely come to a halt as tight regional supply is expected to be alleviated along with the restart of several northeast Asian plants from their scheduled turnarounds.
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MDI: Pure methyl diphenyl diisocyanate (MDI) occurs as white to pale yellow crystals or flakes with a slightly musty odour. It is soluble in acetone, benzene, kerosene and nitrobenzene. It reacts readily with water to form insoluble polyureas and may polymerise under the influence of temperatures above 204oC.
MDI is made available both in pure form and as a mixture of MDI, the dimer and trimer. Mixed MDIs is referred to as polymeric isocyanates or PMDI.
MDI is used mainly in polyurethane (PU) foams. Rigid foams are mostly used in construction, refrigeration, packaging and insulation. Flexible foams are used in furniture, bedding and transportation. MDI is also used to make binders, elastomers, adhesives, sealants and coatings.
TDI: The main outlet for toluene diisocyanate (TDI) is in the manufacture of polyurethane (PU) flexible foams used in upholstery, mattresses and automotive seats. This is achieved by reacting the TDI with a polyol to produce the foam. Smaller uses for TDI include polyurethane elastomers and coatings.
TDI occurs as colourless to pale yellow liquid or crystals with a pungent odour. All isocyanates are hazardous and must be handled with care. Skin contact must be avoided, as redness, blistering and possible sensitisation can result.