Styrene CAS No: 100-42-5

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Styrene is consumed in polystyrene manufacture (source: BASF)Styrene is mainly used in the manufacture of homopolymers and copolymers. These include polystyrene (PS), expandable polystyrene (EPS), styrene copolymers (such as acrylonitrile-butadiene-styrene (ABS) resins, styrene-acrylonitrile (SAN) and styrene-butadiene latexes), styrene-butadiene rubber (SBR) and unsaturated polyester resins.

 

Around half of styrene consumption is used in polystyrene manufacture. High styrene prices as a result of the volatile benzene market have forced PS prices to a level where demand has suffered.

 

Styrene is only growing significantly in China and other developing countries. However, the global styrene market saw a sharp contraction in 2008 due to the economic downturn. Meanwhile, new plants in the Middle East and Northeast Asia will increase the overcapacity in the market.

 

Styrene is produced predominately by ethylbenzene(EB)-based technology. EB is first made by the catalytic alkylation of benzene with ethylene and then dehydrogenated to styrene. The coproduction of styrene with propylene oxide by the PO/SM process had been gaining popularity.

 

Pure styrene is a colourless to yellow, oily liquid that evaporates easily and has a sweet smell. Styrene is highly flammable, forms explosive mixtures in air, is dangerous when exposed to flame, heat or oxidants and on decomposition, emits acrid fumes.

Styrene Price Reports

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Styrene Uses and Outlook

Styrene is mainly used in the manufacture of homopolymers and copolymers. These include polystyrene (PS), expandable polystyrene (EPS), styrene copolymers (such as acrylonitrile-butadiene-styrene (ABS) resins, styrene-acrylonitrile (SAN) and styrene-butadiene latexes), styrene-butadiene rubber (SBR) and unsaturated polyester resins.
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Styrene Process Technologies

Styrene is produced predominately by ethylbenzene(EB)-based technology. EB is first made by the catalytic alkylation of benzene with ethylene, using either aluminium chloride or, more recently, zeolite catalysts. The reaction can be carried out in either vapour or liquid phases (see chemical intelligence report on ethylbenzene).
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Styrene Plants and Projects

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Styrene Synonyms & Abbreviations

  • Estireno
  • Phenylethylene
  • Styrene monomer
  • Vinylbenzene
  • SM

Styrene Properties

Auto-ignition temperature oC
490
Boiling point oC
145
Explosive limits, vol% in air
0.9-6.8
Flash point oC c.c
31
Melting point oC
-30.6
Molecular weight
104.1
Octanol/water partition coefficient (log Pow)
3.2
Relative density (water = 1)
0.9
Relative vapour density (air = 1)
3.6
Vapour pressure, Pa at 20oC
0.7
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