Toluene CAS No: 108-88-3

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The main chemical use of toluene is to make benzene and xylenes using a number of technologies. Toluene is also used in solvent applications and is consumed in the manufacture of toluene diisocyanate (TDI) which is used in the manufacture of polyurethane foams. Toluene can be a raw material for polyurethane elastomers (Source: BASF)

 

More than 50% of toluene demand is used in the production of benzene and xylenes, around 25% in solvents and 7-8% in the TDI, benzoic acid and caprolactam. Around 15% of demand is accounted for by gasoline.

 

The original source of toluene from coke-oven gas has been replaced by the catalytic reforming of naphthas and from pyrolysis gasoline co-produced in the steam cracking of liquid feedstocks. A very small amount is still produced from light oil formed by the carbonisation of coal.

 

Toluene is a colourless, mobile liquid with a characteristic sweet, pungent, benzene-like odour. It is an irritant to the eyes, skin, nose and lungs. Toluene is a dangerous fire hazard and can lead to a flashback due to its heavy vapour.

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Toluene Uses and Outlook

The main chemical use of toluene is to make benzene and xylenes using a number of technologies. In the hydrodealkylation (HDA) process, toluene and hydrogen are reacted to make benzene only. A toluene disproportionation (TDP) plant will convert toluene to benzene and xylenes while there are selective toluene disproportionation (STDP) processes that produce a paraxylene-rich stream. The transalkylation (TA) process takes toluene and C9 aromatics to produce xylenes.
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Toluene Process Technologies

The original source of toluene from coke-oven gas has been replaced by the catalytic reforming of naphthas and from pyrolysis gasoline co-produced in the steam cracking of liquid feeds. A very small amount is still produced from light oil formed by the carbonisation of coal while small quantities are recovered as a byproduct in styrene manufacture.
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Toluene Synonyms & Abbreviations

  • Methacide
  • Methylbenzene
  • Phenylmethane
  • Tolueno
  • Toluol

Toluene Properties

Auto-ignition temperature oC
480
Boiling point oC
111
Explosive limits, vol% in air
1.1-7.1
Flash point oC c.c
4
Melting point oC
-95
Octanol/water partition coefficient (log Pow)
2.69
Relative density (water = 1)
0.87
Relative vapour density (air = 1)
3.2
Vapour pressure, Pa at 20oC
2.9
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