Vinyl Chloride Monomer (VCM) CAS No: 75-01-4

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VCM is used mainly in PVC manufacture (source: Ineos Vinyls)Vinyl chloride monomer (VCM) is used almost exclusively in polyvinyl chloride (PVC) manufacture. PVC itself is highly dependent on the construction market, which reflects the ups and downs of the world economies.

 

The global VCM market has been growing at nearly 4%/year. However, world demand collapsed by 8% in 2008 due to the economic recession and destocking along the vinyls chain. Recovery is unlikely to start until the construction market improves.

 

With the exception of China, nearly all production is now based on ethylene, which is first reacted with chlorine to make ethylene dichloride (EDC). The EDC is then converted to VCM by thermal cracking. In China, the dominant process to make VCM is based on acetylene produced from calcium carbide which is manufactured from coal and limestone.

 

Vinyl chloride is a colourless gas with a characteristic mild, sweet odour. A toxic and hazardous material, vinyl chloride has been classified as a group A, human carcinogen.

Vinyl chloride Price Reports

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Vinyl chloride Uses and Outlook

Vinyl chloride monomer (VCM) is used almost exclusively in polyvinyl chloride (PVC) manufacture. The remainder is consumed in polyvinylidene chloride and chlorinated solvents. With over 98% of VCM used in PVC, VCM demand is very dependent on the fortunes of the PVC market.
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Vinyl chloride Process Technologies

Commercial production of VCM started in the 1920s based on the catalytic hydrochlorination of acetylene but this route suffered from high energy costs and has become obsolete except for China.
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Vinyl chloride Plants and Projects

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Vinyl chloride Synonyms & Abbreviations

  • Chloroethene
  • Chloroethylene
  • Cloruro de vinilo
  • Vinyl chloride monomer
  • VCM

Vinyl chloride Properties

Auto-ignition temperature oC
472
Boiling point oC
-13
Explosive limits, vol% in air
3.6-3.3
Flash point oC c.c
-78
Melting point oC
-154
Molecular weight
62.5
Octanol/water partition coefficient (log Pow)
0.6
Relative density (water = 1)
0.9
Relative vapour density (air = 1)
2.2

 
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